For vibrational states, the Boltzmann equation can be written as where N 0 and N 1 are the…

For vibrational states, the Boltzmann equation can be
written as

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For vibrational states, the Boltzmann equation can be written as where N 0 and N 1 are the…
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where N0 and N1 are the populations of
the lower and higher energy states, respectively, DE is the energy difference
between the states, k is Boltzmann’s constant, and T is the temperature in
kelvins.

For temperatures of 20°C and 40°C, calculate the ratios of
the intensities of the anti-Stokes and Stokes lines for CCl4 at (a)
218 cm-1 , (b) 459 cm-1 , (c) 790 cm-1 .

For each temperature and Raman shift, calculate how much
more intense the Stokes line is compared to the anti-Stokes line.

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