Insert a reverse reaction in the second step of the mechanism of Eq. (13.1-16), assuming a single…

Insert a reverse reaction in the second
step of the mechanism of Eq. (13.1-16), assuming a single product, P, and
assuming that the reverse reaction in step 2 is elementary.

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Insert a reverse reaction in the second step of the mechanism of Eq. (13.1-16), assuming a single…
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a. Write an expression for the equilibrium
constant of the reaction in the absence of the catalyst.

b. Write an expression for the equilibrium
constant in terms of the rate constants in the assumed mechanism. Express the
rate constant for the reverse reaction of step 2 in terms of the other rate
constants and the equilibrium constant, using the principle of detailed
balance.